The sabatier principle in electrocatalysis: Basics, limitations, and extensions H Ooka, J Huang, KS Exner Frontiers in Energy Research 9, 654460, 2021 | 338 | 2021 |
Controlling Selectivity in the Chlorine Evolution Reaction over RuO2‐Based Catalysts KS Exner, J Anton, T Jacob, H Over Angewandte Chemie 41, 11212-11215, 2014 | 245 | 2014 |
Kinetics of electrocatalytic reactions from first-principles: a critical comparison with the ab initio thermodynamics approach KS Exner, H Over Accounts of chemical research 50 (5), 1240-1247, 2017 | 169 | 2017 |
A universal approach to determine the free energy diagram of an electrocatalytic reaction KS Exner, I Sohrabnejad-Eskan, H Over Acs Catalysis 8 (3), 1864-1879, 2018 | 156 | 2018 |
Full Kinetics from First Principles of the Chlorine Evolution Reaction over a RuO2(110) Model Electrode KS Exner, J Anton, T Jacob, H Over Angewandte Chemie International Edition 55 (26), 7501-7504, 2016 | 148 | 2016 |
Beyond the Rate-Determining Step in the Oxygen Evolution Reaction over a Single-Crystalline IrO2 (110) Model Electrode: Kinetic Scaling Relations KS Exner, H Over ACS Catalysis 9, 6755-6765, 2019 | 147 | 2019 |
Temperature-Dependent Kinetic Studies of the Chlorine Evolution Reaction over RuO2(110) Model Electrodes I Sohrabnejad-Eskan, A Goryachev, KS Exner, LA Kibler, EJM Hensen, ... ACS Catalysis 7 (4), 2403-2411, 2017 | 130 | 2017 |
A universal descriptor for the screening of electrode materials for multiple-electron processes: beyond the thermodynamic overpotential KS Exner ACS Catalysis 10 (21), 12607-12617, 2020 | 126 | 2020 |
Chlorine evolution reaction on RuO2 (110): Ab initio atomistic thermodynamics study-Pourbaix diagrams KS Exner, J Anton, T Jacob, H Over Electrochimica Acta 120, 460-466, 2014 | 121 | 2014 |
Is Thermodynamics a Good Descriptor for the Activity? Re-Investigation of Sabatier’s Principle by the Free Energy Diagram in Electrocatalysis KS Exner ACS Catalysis 9, 5320-5329, 2019 | 114 | 2019 |
Does a thermoneutral electrocatalyst correspond to the apex of a volcano plot for a simple two‐electron process? KS Exner Angewandte Chemie 132 (26), 10320-10324, 2020 | 109 | 2020 |
Ligand Effects and Their Impact on Electrocatalytic Processes Exemplified with the Oxygen Evolution Reaction (OER) on RuO2(110) KS Exner, J Anton, T Jacob, H Over ChemElectroChem 2 (5), 707-713, 2015 | 75 | 2015 |
Controlling Stability and Selectivity in the Competing Chlorine and Oxygen Evolution Reaction over Transition Metal Oxide Electrodes KS Exner ChemElectroChem 6, 3401-3409, 2019 | 69 | 2019 |
Recent progress in the development of screening methods to identify electrode materials for the oxygen evolution reaction KS Exner Advanced Functional Materials 30 (42), 2005060, 2020 | 62 | 2020 |
Design Criteria for Oxygen Evolution Electrocatalysts from First Principles: Introduction of a Unifying Material-Screening Approach KS Exner ACS Applied Energy Materials 2, 7991-8001, 2019 | 61 | 2019 |
Beyond the Traditional Volcano Concept: Overpotential-Dependent Volcano Plots Exemplified by the Chlorine Evolution Reaction over Transition-Metal Oxides KS Exner The Journal of Physical Chemistry C 123, 16921-16928, 2019 | 60 | 2019 |
General efficacy of atomically dispersed Pt catalysts for the chlorine evolution reaction: potential-dependent switching of the kinetics and mechanism T Lim, JH Kim, J Kim, DS Baek, TJ Shin, HY Jeong, KS Lee, KS Exner, ... ACS Catalysis 11 (19), 12232-12246, 2021 | 53 | 2021 |
Paradigm change in hydrogen electrocatalysis: The volcano's apex is located at weak bonding of the reaction intermediate KS Exner International Journal of Hydrogen Energy 45 (51), 27221-27229, 2020 | 51 | 2020 |
Design criteria for the competing chlorine and oxygen evolution reactions: avoid the OCl adsorbate to enhance chlorine selectivity KS Exner Physical Chemistry Chemical Physics 22 (39), 22451-22458, 2020 | 51 | 2020 |
Why approximating electrocatalytic activity by a single free‐energy change is insufficient KS Exner Electrochimica Acta 375, 137975, 2021 | 49 | 2021 |